Diffusion in nanopores: inspecting the grounds
نویسندگان
چکیده
منابع مشابه
The Technological Impact of Diffusion in Nanopores
The impact of nanopore diffusion on the performance of adsorption separation processes is reviewed. Zeolite membrane processes and kinetically selective cyclic adsorption processes depend for their selectivity on differences in intracrystalline diffusion rates so these processes are designed to operate under conditions of intracrystalline diffusion control. In contrast, the performance of equil...
متن کاملHydrodynamic origin of diffusion in nanopores.
We study the transport of a subcritical Lennard-Jones fluid in a cylindrical nanopore, using a combination of equilibrium and nonequilibrium as well as dual control volume grand canonical molecular dynamics methods. We show that all three techniques yield the same value of the transport coefficient for diffusely reflecting pore walls, even in the presence of viscous transport. We also demonstra...
متن کاملSimulating Microwave-Heated Diffusion in Zeolite Nanopores
Zeolites are nanoporous crystalline alumino-silicates with a rich variety of interesting properties and industrial applications. With over 140 zeolite framework topologies synthetically available—each with its own range of compositions—zeolites offer size-, shapeand electrostaticallyselective adsorption, diffusion and reaction up to remarkably high temperatures. Zeolites are widely used as petr...
متن کاملEnhanced ionic diffusion in ionomer-filled nanopores.
Coarse-grained simulations in the united-atom-model approximation are used to investigate confinement-induced morphological changes in Nafion-like ionomers. The system we study models a cylindrical pore in a hydrophobic matrix of supporting material with pore diameters that vary from 0.7 to 3.96 nm. Simulation results indicate a strong dependence of the equilibrium ionomer structures both on th...
متن کاملMolecular simulation of protein dynamics in nanopores. II. Diffusion.
A novel combination of discontinuous molecular dynamics and the Langevin equation, together with an intermediate-resolution model of proteins, is used to carry out long (several microsecond) simulations in order to study transport of proteins in nanopores. We simulated single-domain proteins with the alpha-helical native structure. Both attractive and repulsive interaction potentials between th...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Adsorption
سال: 2020
ISSN: 0929-5607,1572-8757
DOI: 10.1007/s10450-020-00277-6